普通磷矿粉与超细磷矿粉在不同有机酸中的溶解特性
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S143.2+2

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国家科技支撑计划项目(2011BAD11B04)


Dissolution Characteristic of Ordinary and Ultra-Fine Ground Phosphate Rock in Different Organic Acids
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    摘要:

    本文采用分别代表沉积、内生、变质3种类型的6个中低品位磷矿,制成普通磷矿粉(PR)和超细磷矿粉(MPR)。使用连续浸提法研究了PR和MPR在柠檬酸、甲酸、草酸、酒石酸的溶解特性。结果表明:无论是PR还是MPR,释放磷最高峰基本都在第一次,只有4种普通磷矿粉在2%柠檬酸连续浸提时最高峰出现在二次或第三次;PR在柠檬酸、甲酸、酒石酸的溶解沉积型磷矿粉释放最快,MPR在4种酸中变质型磷矿粉释放较快;MPR不论在何种酸中都比PR释放总量大且快,表明磷矿粉磷释放量与粒径关系密切,粒径减小显著增加了磷释放量,MPR比PR提高倍数柠檬酸、甲酸、酒石酸的规律相近,都是沉积型<内生型<变质型。

    Abstract:

    In this investigation of the nutrient release characteristics of treated phosphate rock, six low grade phosphate rock representing three types of sedimentary, endogenous, metamorphic were used in the laboratory to make into ordinary ground phosphate rock(PR) and ultra-fine phosphate rock(MPR) to study the dissolution characteristics of PR and MPR in citric acid, formic acid, oxalic acid and tartaric acid using continuous extraction method.The results showed that the highest peak of release phosphorus for both PR and MPR appeared at the first time, and four ordinary rock phosphate in 2% citric acid successive extraction phosphorus peak occurred at the secondary or third time. For PR, sedimentary PR had the fastest solution in citric acid, formic acid, tartaric acid, while for MPR was metamorphic rock phosphate. In all types of acid, MPR released more and faster phosphorus than PR, which indicated that the release of phosphate was closely related to phosphate particle size. Smaller particle size can increase the rate of phosphate released. The increased rates for MPR to PR were similar in citric acid, formic acid and tartaric acid, and the order were as follows: sedimentary type < endogenous type < metamorphic type.

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李雪梅,石元亮.普通磷矿粉与超细磷矿粉在不同有机酸中的溶解特性[J].东北农业科学,2014,39(5):58-61,89.

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  • 收稿日期:2014-04-08
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  • 在线发布日期: 2024-12-06
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