Based on the analysis of the current situation of e-commerce poverty alleviation in Dangshan County, the survey of the e-commerce poverty-stricken areas in Dangshan County was summarized, and the specific optimization path was proposed. The study found that the effect of e-commerce poverty alleviation in Dangshan County is remarkable. There are dilemmas of low participation in poverty alleviation, insufficient integration with other forms of poverty alleviation, lack of e-commerce and poverty alleviation platforms, and scarcity of e-commerce and poverty alleviation.The existing path should be optimized from the aspects of strengthening the main mobilization, coordinating the forms of poverty alleviation, cultivating the lower level platform and cultivating the e-commerce talent, so as to promote the further development of the e-commerce poverty alleviation.